I checked his vent before he went in, and I'm pretty sure the other is female from glimpses of her vent in the tank
Ok. Here are you trying to say that you determined the sex of the oscars by looking at them? Because this is impossible, the only way to tell their sex is when they are mating.
And you said you went home and filled the tank right up, does this mean you didn't cycle the tank? If not please read
oscarfishlover.com/helpful-articles/cycling-an-aquarium
Cycling the tank is EXTREMELY important and you will likely lose fish if your tank is not cycled before adding them, especially full grown oscars, because they produce so much waste, which breaks down into highly toxic ammonia. You may want to consider getting the beneficial bacteria from another source, such as existing tank media. If the tank is already cycled then ignore my babbling, if not, please read the article and it may be necessary to take the fish out until the tank is cycled, they may live through a cycle but it is very stressful for them and very likely to kill them.