Just wanted to share it went very well, although there was a few things that went not as expected.
For the initial task I moved things around in the tank and turned the lights off. I then added the new Oscar (now named Boss) to the tank, splash of water everywhere but that was expected.
Boss went to the bottom and pouted for a few minutes then decided to take a browse around the tank.
Initial contact between Boss and Silent Bob were very calm, just a brush up against one another and then off in their own directions.
After about 24 hours in the tank I decided to try a feeding, and Silent Bob decided to eat everything as he punked the much bigger Boss for his food. Again this morning I attempted to give Boss some food only to have Silent Bob snag it all up...then it must have become an issue with Boss as he chased Silent Bob around the tank until he spit out the food (he had more than he could chew).
So far the two seem to be getting along pretty well, I am very happy with how it turned out and Boss is a great addition.