Actually, your tank is cycling. You will need to do regular water changes and make sure the dechlorinator has kicked in before letting the water circulate through your filter.
Ammonia and Nitrite should always be at zero on a cycled tank. Change water to keep nitrates below 20, below 10 if you can.
As the cycle kicks in, nitrites will start to rise and the ammonia will start to go to zero. Then after a bit longer, nitrates will start to rise and nitrite will start to zero out.
To help, you can feed lightly, make sure all uneaten food is removed ... so them not eating is not a bad thing.
Oscar have a lot of personality, so the hide, play dead - sometimes stopping mid swim, turning on their side and floating down like a leaf.
Some are more apprehensive to new environments and new owners than others. Some, the water parameters affect them more.
Give it some time for your tank to cycle and them to get used to you. Soon enough, they will be begging all the time. Also, check what kind of food the store fed, not that you need to switch to it, but in the rare occasion they gave them 'treat' type food, the initial transition can be harder. Most places don't because bloodworms, krill, daphnia, and all that tasty to Os stuff is more expensive.
They won't starve themselves, trust in that. You might see them hungry today if they haven't eaten anything yet, if not the next couple days. I say stick with the pellets, they are much better nutrition wise.
They will soon associate you with food, I have train mine to recognize the different containers. He knows which pellets come from which bags, knows the freeze dried krill container, knows the frozen bloodworm foil pack, and exhibits different levels of begging for each one
Try to be patient at first, and keep you eye on that ammonia and nitrite.
Best wishes.